As Bond and Honey Ryder make their way to dinner in Dr. No’s lair in the first James Bond movie Dr. No (1961), you’ll notice 007 do a double-take on a particular piece of artwork before walking up some stairs:
The painting (Portrait of the Duke of Wellington by Francisco de Goya) was notable at the time of the movie as a pop culture reference, since in real life it was stolen. Bond’s look at the painting shows his surprise that Dr. No is the perpetrator.