The first five seconds of Skyfall (2012) may be the best start of any Bond movie.
Bond and Kerim Bey are about to assassinate a Russian agent during a pivotal sequence in From Russia With Love (1963), when an interesting movie poster crops up in the foreground of a building:
“Harry Saltzman Albert R. Broccoli Present”? Is this another Bond movie?!
Nope, it’s a poster for Call Me Bwana (1963), the only other non-James Bond produced Eon Productions movie. It was a farce film that starred Bob Hope and Anita Ekberg. Check out its bizarre plot at its Wikipedia page. Cool huh?
Scaramanaga’s third nipple in The Man With The Golden Gun (1974)
Bond’s (fake) third nipple in The Man With The Golden Gun (1974) to assume Scaramanga’s identity
Scaramanga couldn’t have had a distinctive beauty mark?!
MRW seeing the third nipples in The Man With The Golden Gun (1974)
Seriously!

Cannot abort the missile aboard the HMS Chester! From Tomorrow Never Dies (1997)
Daniel Craig’s James Bond takes a shortcut through some drywall chasing Mollaka in Casino Royale (2006).
(Family Guy references the Kool-Aid guy commercials.)
(Check out the street sweeper in the background.)
Phuket, Thailand from The Man With The Golden Gun (1974) has to be one of the top five James Bond movie locations…just amazing!